Two sets of iron oxide samples were synthesized applying different iron(III) precursors (FeCl₃ and Fe₂(SO₄)₃) and calcination temperature (200, 300, and 500°C). The samples were characterized by powder X-ray analysis and the Fourier transform infrared spectroscopy. Depending on the synthesis conditions, samples of iron oxides with different phase composition were obtained: polyphase (α -Fe₂O₃, γ -Fe₂O₃, Fe₃O₄, and α -FeO(OH)) and monophase (γ -Fe₂O₃ or α -Fe₂O₃) ones. For the samples of homogeneous composition, it has been found that the activity of γ -Fe₂O₃ in the reaction of ozone decomposition at ozone concentration in gaseous phase of 1 mg/m³ is much higher than the activity of α -Fe₂O₃.
Samples of natural bentonite and clinoptilolite modified with copper(II), iron(III), and palladium(II) were characterized by both X-ray phase and the Fourier transform infrared spectral methods. The activity of monometallic compositions M_{i}L_{j}/S(M = Co(II), Fe(III), and Pd(II); L = NO₃¯, Cl¯, and SO₄²¯; S = N-CLI or N-Bent) in the reaction with sulfur dioxide was found to depend on the nature of both a metal ion and a support. For bimetallic compositions Cu(II)-Fe(III) and Cu(II)-Pd(II) based on the natural aluminosilicates, a certain synergism in the action of metals forming these pairs towards the reaction of sulfur dioxide oxidation with oxygen was determined.
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.