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  1. 1 Acta Physica Polonica A

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  1. 1 1994

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  1. 1 Jain V.

  2. 1 Takhur S.

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Electron Paramagnetic Resonance of Cr^{3+} in Rb_{x}(NH_{4})_{1-x}Al(SO_{4})_{2}·12H_{2}O

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Takhur S., Jain V.
Acta Physica Polonica A
|
1994
|
vol. 85
|
issue 6
985-988
EN
The EPR of Cr^{3+} in mixed alum Rb_{x}(NH_{4})_{1-x}Al(SO_{4})_{2}·12H_{2}O has been studied at ca. 300 K and ca. 9.45 GHz. The EPR spectrum for x between 30 to 70% shows more than one kind of chromium complexes. The variation in magnitude of zero-field splitting parameter D indicates that the monovalent ions probably play an important role in the trigonal distortion of the water octahedron around the trivalent metal ion in alums.
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