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  1. 1 Open Chemistry

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  1. 1 2013

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  1. 1 Mendoza-Huizar L.

  2. 1 Rios-Reyes C.

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Cobalt electrodeposition onto polycrystalline gold from ammoniacal solutions

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Mendoza-Huizar L., Rios-Reyes C.
Open Chemistry
|
2013
|
vol. 11
|
issue 8
1381-1392
EN
In the present work, the cobalt electrodeposition onto polycrystalline gold electrodes from aqueous solutions containing 0.01M CoSO4 + 1 M (NH4)2SO4 at pH=7 was analyzed. Linear voltammetry results suggested a change in the kinetic of the cobalt electrodeposition. In all cases, the nucleation rate (A), the number of active nucleation sites (N 0) and the saturation number of nuclei (N s ) values were potential dependent. The calculated Gibbs free energy (ΔG) for this system was 1.88×10−20 J nuclei−1 and the transfer coefficient for the Hydrogen Electroreduction Reaction (HER) was 0.47. [...]
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