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EN
A developed model of commercial thermoelectric refrigerators with finned heat exchanger is established by introducing finite time thermodynamics. A significant novelty is that physical properties, dimension parameters, temperature parameters and flow parameters are all taken into account in the model. Numerical studies and comparative investigation on the performance of a typical commercial water-cooling thermoelectric refrigerator which consists of 127 thermoelectric elements, are performed for cooling load and coefficient of performance. The results show that the maximum cooling load is 2.33 W and the maximum coefficient of performance is 0.54 when the cooling temperature difference is 10 K. Comparing the simulation results of several models, it is found that the heat convection of the heat exchanger and the heat leakage through the air gap are the main factors, which cause irreversibility and decrease the performance. Moreover, the performance can be improved by optimizing the length and cross-section area of thermoelectric elements. The model and calculation method may be applied to not only the analysis and performance prediction of practical thermoelectric refrigerators, but also the design and optimization of heat exchangers.
EN
The performance of an isothermal endoreversible four-reservoir chemical potential transformer, in which the mass transfer between the mass reservoir and the working medium obeys diffusive law, is analyzed and optimized in this paper. The relation between the rate of energy pumping and the coefficient of performance of the isothermal chemical potential transformer is derived by using finite-time thermodynamics. Moreover, the optimal operating regions and the influences of some parameters on the performance of the cycle are studied. The results obtained herein can provide some new theoretical guidelines for the optimal design of a class of apparatus such as mass exchangers, as well as electrochemical, photochemical, and solid-state devices, and the fuel pumps for solar-energy conversion systems.
EN
A multistage endoreversible Carnot heat engine system operating between a finite thermal capacity high-temperature fluid reservoir and an infinite thermal capacity low-temperature environment with a generalized heat transfer law [q ∝ ( Δ (T^{n}))^{m}] is investigated in this paper. Optimal control theory is applied to derive the continuous Hamilton-Jacobi-Bellman equations, which determine the optimal fluid temperature configurations for maximum power output under the conditions of fixed initial time and fixed initial temperature of the driving fluid. Based on the general optimization results, the analytical solution for the case with Newtonian heat transfer law [q ∝ Δ(T)] is further obtained. Since there are no analytical solutions for the other heat transfer laws, the continuous Hamilton-Jacobi-Bellman equations are discretized and the dynamic programming algorithm is adopted to obtain the complete numerical solutions of the optimization problem, and the relationships among the maximum power output of the system, the process period and the fluid temperature are discussed in detail. The results show that the optimal high-temperature fluid reservoir temperature for the maximum power output of the multistage heat engine system with Newtonian and linear phenomenological [q ∝ Δ (T^{-1})] heat transfer laws decrease exponentially and linearly with time, respectively, while those with the Dulong-Petit [q∝(Δ T)^{1.25}], radiative [q∝ Δ (T^4)] and [q∝(Δ(T^4))^{1.25}] heat transfer laws are different from the former two cases significantly.
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