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  1. 1 Acta Physica Polonica A

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  1. 1 1999

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  1. 1 Hamaguchi H.

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Recent Developments in Ultrafast Time-Resolved Vibrational Spectroscopy of Electronically Excited States

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Hamaguchi H.
Acta Physica Polonica A
|
1999
|
vol. 95
|
issue 1
37-48
EN
Developments of three new time-resolved vibrational spectroscopies and their applications to electronically excited states are reviewed. Transformlimited picosecond time-resolved Raman spectroscopy has been used to study the vibrational dynamics of trans-stilbene in the lowest excited singlet state. Picosecond time-frequency two-dimensional multiplex Coherent Antistokes Raman Scattering spectroscopy has been used to probe the structure of diphenylacetylene in the lowest and the second lowest excited singlet states. Nanosecond time-resolved dispersive infrared spectroscopy has detected the singlet and triplet intramolecular charge transfer states of 4-(di-methylamino)benzonitrile. Strong evidence for a charge transfer structure has been obtained.
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