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The phenomenon of Fano type resonant photoemission was used to distinguish the Fe electrons derived partial contribution to the valence band of a semimagnetic semiconductor Cd_{1-x}Fe_{x}Se. The states appearing at the middle of the valence band correspond to the Fe 3d electrons while the step of the density of states obtained at the valence band edge region correspondsvto the hybridized s-p-d electrons.
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