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Investigation of complex formation reactions of Fe(III) and Al(III) with some phenol derivatives by the method of ion exchange

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Masłowska J., Piętek W., Łódź T. U. o.
Acta Universitatis Lodziensis. Folia Chimica
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1982
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vol. 1
EN
By the method of ion exchange on the exchanger Dowex 50 WX 8 100-200 mesh complex formation was investigated in the system Me(ClO₄)₃ + XC₆H₄OH + HClO₄ + NaClO₄ + H₂O, with Me = Fe(III) or Al(III) and X = Cl, Br, CH₃, NO₂. It was proved that 1:1 complexes are formed between Me(III) and a phenol molecule. Stability constants of the complexes were determined and related with Hammett’s sigma constants.
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