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Synthesis and characterization of Mn-, La-Mn- and La-Ca-Mn-citrates as precursors for LaMnO3 and La1−xCaxMnO3

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Petrova N., Todorovsky D., Vasileva V.
Open Chemistry
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2005
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vol. 3
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issue 2
263-278
EN
Mn-, LaMn- and LaCaMn-citrates were synthesized at 60–120°C in ethylene glycol medium using chlorides or nitrates as metal sources. Their composition, IR spectra and thermal decomposition were studied. Equimolar La/Mn ratio has been established in the complex, prepared from chloride solution with the same initial composition of the metals. In the isolated three-metallic complex the molar ratio of the metals deviates from the composition in the initial solution. The final products of the heating of Mn- and mixed-metal LaMn-citrates at 1000°C are phase-homogeneous Mn3O4 (hausmannite) and LaMnO3 respectively. Parasitic phase(s) are observed in LaxCa1−xMnyO3, produced from LaCaMn-citrate.
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Synthesis and characterization of Al-and Y-Al-citrates as potential precursors for YAlO3

100%
Petrova N., Todorovsky D., Kovacheva D., Milanova M.
Open Chemistry
|
2006
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vol. 4
|
issue 4
632-645
EN
Al-and Y-Al-citric complexes have been synthesized in ethylene glycol medium at conditions close to the ones used in polymerized complex method and their composition and spectral characteristics have been studied. Proofs have been found for the formation in the bimetallic system of a mixed-metal Al-Y-complex. Doubly ionized and esterified ligands take place in the Al-complex. All of the ligands forming Y-Al-complex are mono-or doubly esterified. Deprotonation of the alcoholic group takes place in the formation of the mixed-metal complex. Both complexes contain adduct-bonded ethylene glycol. Heating of the bimetallic complex or of the polyester resin formed leads to not phase-homogeneous YAlO3-along with cubic YAlO3, its orthorhombic modification as well as Y4All2O9 are found by X-ray diffractometry.
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