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^1H NMR Study of Molecular Dynamics of 4-apyH Cation under High Hydrostatic Pressure

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Medycki W., Świergiel J., Jakubas R., Hołderna-Natkaniec K.
Acta Physica Polonica A
|
2005
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vol. 108
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issue 1
161-164
EN
Polycrystalline [4-NH_2C_5H_4NH] SbCl_4 and [4-NH_2C_5H_4NH] SbCl_6 have been investigated by proton NMR methods between 120 K and 370 K under hydrostatic pressure of 0.1 and 520 MPa. Reduction in the dipolar second moment is interpreted in terms of cation reorientation. Activation energies characterizing the motion increase with increasing pressure.
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