We have analyzed the Co influence on the absorption spectra of (80-x)Sb_2O_3-20Na_2O-xWO_3 glasses in the Urbach rule region at room temperature. We present the comparison between Co and WO_3 manifestation in the spectral region 2.64-3.14 eV. The spectral characteristics of "crystalline" and "glassy" Urbach's rule are also calculated.
The absorption spectrum of Bi_{12}SiO_{20}:Cu is measured in the spectral region 0.195-2.95 eV. The validity of the Urbach rule (2.08-2.95 eV) has been also verified. The photochromic effect of these samples in far IR region is investigated. The energy level diagram of Cu^{3+} cations in Bi-octahedrons is presented.
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