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EN
In the paper technological conditions were looked for to obtain the Pb(Fe_{1/2}Nb_{1/2})O_{3} (PFN) ceramics and the PFN ceramics with the lithium admixture with the highest electric conduction and conditions appropriate for the PTC-R effect formation. Measurements of dc electrical resistivity, dielectric permittivity and dielectric loss were made as functions of temperature from room temperature to 190°C, at 1 kHz. The best set of values of dielectric loss and dielectric constant, from the ferroelectricity point of view, were obtained when the precursor with orthorhombic structure was employed. By creating appropriate technological conditions in the PFN ceramics the PTC-R effect can occur above the Curie temperature. Their electric properties are determined by presence of a basic phase of the potential barrier on the grain boundaries.
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2008
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vol. 114
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issue 6A
A-15-A-20
EN
The PbFe_{1/2}Nb_{1/2}O_3 (PFN) ceramics can be obtained by a lot of ways. There are a lot of methods and techniques to synthesize the PFN powder such as: reactions in the solid phase by one-stage or two-stage synthesizing method (the columbite method), molten salt synthesis, sol-gel, co-precipitation method and sintering of compacts from a loose mixture of powders. Each of them requires accuracy and precision to conduct a technological process, aiming at obtaining a product with the optimum parameters. In the work PFN specimens were obtained by one-stage synthesis methods using two different powder synthesizing techniques: by calcining (sintering of a loose mixture of the PFN powder) and as a result of sintering of pressed compacts from the PFN powder mixture at high temperature (pressing). The obtained specimens were subjected to X-ray and micro-structural examinations and tests of internal friction and dielectric properties. The tests showed that the ceramics obtained by the powder calcining method has better applied properties.
EN
In the work tests of the influence of the technological conditions on the basic applied properties of the Pb(Fe_{0.5}Nb_{0.5})O_3 ceramics were carried out. The Pb(Fe_{0.5}Nb_{0.5})O_3 specimens were obtained by a two-stage method of synthesizing (the niobite method), a technique of the powder mixture calcinations, changing a temperature range of the iron-niobate (FeNbO_{4}), whereas compacting was conducted by free sintering.
EN
In this work an attempt was made to obtain three compositions of the solid solution (1-x)Pb(Fe_{0.5}Nb_{0.5})O_{3}-(x)BiFeO_{3} for x=0.8, 0.7 and 0.6. The obtained specimens were subjected to microstructure and dielectric examinations and temperature dependences of the internal friction Q^{-1}(T) and Young's modulus E(T).
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