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The effects of iron additions on the structure of (Cu_{0.47}Ti_{0.34}Zr_{0.11}Ni_{0.08})_{100-x}Fe_{x} (x=0, 1.5, 3, 6) glass forming system are presented. The alloys were synthesized by arc melting of high purity elements and melt spun to form: rapidly quenched ribbons. X-ray diffraction studies showed the amorphous structure of the base and Fe-containing alloys, confirmed by the presence of exothermic peaks on differential scanning calorimetry curves. Bulk samples in the form of rods (Φ3×55 mm) were cast using a suction casting unit attached to the arc melter. Structural investigations revealed partial crystallization of the base Cu₄₇Ti₃₄Zr₁₁Ni₈ alloy. Iron additions significantly decreased the glass forming ability of the alloy, leading to primary crystallization of dendrites.
EN
ArcMelter furnace is commonly used as a method for synthesis of amorphous and nanocrystalline materials. Due to easy and precise chemical composition control, also short time of whole process, this method was used to synthesis of new model hypereutectoid iron alloys. Material for the investigation was 90CrV6 steel. The chemical composition of this steel was modified to obtain the increase of carbides volume fraction with preserving the same chemical composition and mechanical properties of the matrix. The melt was conducted at sub atmospheric pressure of argon. The obtained materials were chemically analyzed by the use of optical emission spectrometer. The metallographic analysis was performed by the use of microscope. Phase composition in cast state was analyzed by X-ray diffraction. Chemical composition of the ingots differed from the previously established compositions in the range of 0.08 mass percentage. The high cooling rate resulted in dendritic character of the obtained microstructures. The microstructure of modified tool materials was plate martensite with large amount of retained austenite. The stress induced martensitic transformation in the crack area was observed. Retained austenite destabilization was initiated by the stress relaxation related with material cracking.
EN
Al₁₅Ti₂₀Co₂₀Ni₂₅Fe₂₀ alloy, synthesized in an arc furnace, was characterized by microscopic investigations, X-ray diffraction and electron backscatter diffraction techniques. Theoretical assumptions indicate a dual-phase crystal structure fcc+bcc. It was shown that dendrites and eutectic are bcc phase, and the interdendritic region is fcc phase.
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