Electronic states of 4f samarium ions were investigated by photoemission spectroscopy in samarium-rich CdSmTe sample obtained by MBE. The photon energy of synchrotron radiation allowed to investigate Fano-type resonance and antiresonance. The energy distribution curve spectra were attributed to the Sm 4d-4f transition. The shape of the constant initial states spectra was compared with this one obtained for atomic samarium.
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