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Acta Physica Polonica A
|
1999
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vol. 96
|
issue 2
275-281
EN
In this paper the studies of phase transitions in some material compositions based on Al_{2}O_{3} caused by high-temperature processes are presented. These material compositions may be used to high-temperature resistant plasma sprayed coatings. The occurring phase transitions are studied by X-ray diffraction methods. Phase transitions and thermal resistance for studied oxide systems are different. In the coatings from the materials belonging to Al_{2}O_{3}-NiO and Al_{2}O_{3}- ZrO_{2} systems complex phase transitions were observed. More resistant to the conditions of thermal fatigue are coatings containing aluminum titanate Al_{2}TiO_{5} and mullite 3 Al_{2}O_{3}-2 SiO_{2}.
EN
New data about the structure of high-temperature resistant metalloceramic plasma sprayed coatings in micro and nano areas are presented. Application of the new instrumental methods: transmission electron microscopy combined with selected area electron diffraction made it possible to obtain these data. The first layer in Ni based metallic bondcoat shows nanocrystalline structure. External ceramic layer based on stabilised ZrO_2 is polycrystalline and contains both cubic and tetragonal crystalline phases. Local inhomogeneities in coatings phase composition are determined.
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2012
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vol. 122
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issue 2
405-409
EN
Composites based on Al_2O_3 and ZrO_2 are used. Coatings deposited by plasma spraying technology are studied with the use of X-ray diffraction and electron microscopy combined with electron diffraction methods. Phase transitions and specific coatings layered microstructure with local fluctuations of phase and chemical composition are connected with the conditions of plasma spray process.
EN
Conductivity and structure of materials belonging to pseudo-binominal group (AgI-Ag_2MoO_4) were investigated. Structure was investigated by X-ray and scanning electron microscopy techniques. It was found that described materials present a variety of internal structures. This type of structures affects conductivity at room temperature, so there is correspondence between conductivity and structure.
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