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Spectroscopic Studies of Neodymium and Europium Phosphoro-azo β-Diketonates

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Amirkhanov V., Ovchinnikov V., Legendziewicz J., Graczyk A., Hanuza J., Macalik L.

Acta Physica Polonica A

1996

vol. 90

issue 2

455-460

New complexes of lanthanides (Nd, Eu) with phosphoro-azo derivatives of β-diketones were synthesized. Optical properties of these compounds were investigated and confronted with the structure and single crystal spectra of different types of earlier reported lanthanide phosphoro-azo-β-diketonates. The exchange of the N-P-O-Me ligand group by the N-P-NR_{2} one plays only a minor role in binding character of lanthanide ions but strongly affects biological functions and properties of lanthanide systems. In vitro experiment on cytotoxicity of the samples was performed using 10T_{1/2}, L_{1}, MCF, DETA and Meω-132 cell lines.

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1 Acta Physica Polonica A

1 1996

1 Amirkhanov V.

1 Graczyk A.

1 Hanuza J.

1 Legendziewicz J.

1 Macalik L.

1 Ovchinnikov V.

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Spectroscopic Studies of Neodymium and Europium Phosphoro-azo β-Diketonates