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  1. 1 Acta Physica Polonica A

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  1. 1 1995

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  1. 1 Barsukov V.

  2. 1 Chivikov S.

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Simple Model for Elucidation the Nature of Current-Generating Processes in Polyaniline-Type Conductive Polymers

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Barsukov V., Chivikov S.
Acta Physica Polonica A
|
1995
|
vol. 87
|
issue 4-5
905-908
EN
According to suggested simple model in the practically important po­tential range (E ≈ 0... + 0.6 V against SHE) the nature of the electro­chemical current-generating processes in conductive polymers of polyaniline type is not associated with a particular redox reaction, but it reduces to the charge/discharge of the double electric layer capacity, which is anomalously high (300... 850 F/g) in such systems due to structural peculiarities of these materials. The model gives a good fit to electrode behavior in this range.
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