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Dielectric Spectroscopy Studies of 4-Cyano-3-fluorophenyl 4-Butylbenzoate Liquid Crystal at High Pressure

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Rozwadowski T., Massalska-Arodź M., Juszyńska E., Krawczyk J., Wojnarowska Ż., Paluch M.
Acta Physica Polonica A
|
2012
|
vol. 122
|
issue 2
378-381
EN
For 4-cyano-3-fluorophenyl 4-butylbenzoate, nematic glassformer at ambient pressure, dielectric relaxation studies were performed under elevated pressure. In the isobaric experiment, on cooling the nematic phase two superarrhenius α-relaxations, ascribed to the reorientations of molecules around short axes and precession of long molecular axes were found and the Arrhenius β-relaxation related to intramolecular motions. Complexity of dynamics at elevated and ambient pressure is similar. Shift towards lower frequencies was found for both α-relaxations.
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