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TEM Observation of Cu and Ag Added Al-Mg-Si Alloy

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EN
It is well known that Cu and Ag addition on Al-Mg₂Si alloy can enhance its mechanical properties due to solid solution hardening. Several reports are available about the effect of each alloying elements, Cu and Ag, on Al-Mg-Si alloys. In this research, Al-Mg-Si-Cu-Ag alloys have chemical compositions of (1) 0.18Cu-0.18Ag and (2) 0.35Cu-0.35Ag [at.%] fixed Cu/Ag rate of 1.0 are prepared using casting to estimate effects of Cu and Ag amount to precipitation behaviour and mechanical properties. The Vickers microhardness measurement was conducted to estimate mechanical property after ageing treatment microstructure observation was carried out using transmission electron microscopy. In peak-aged at 473 K hardness of each alloys was almost the same, but in peak-aged at 523 K, hardness of 0.35Cu-0.35Ag was higher than 0.18Cu-0.18Ag alloy.
EN
Traditionally, Al-Mg-Si alloys are strengthened by dispersed small particles and they have medium strength with good formability. It is well known that alloying elements on Al-Mg-Si alloys (e.g. Cu) can improve mechanical properties because Cu can alter precipitation sequence. In this research, we investigated the effect of transition metals (TM) on Al-1.06at.%MgSi-TM alloys through single- and two-step ageing. Mechanical property and microstructure observation were conducted by micro Vickers hardness measurement and transmission electron microscopy.
EN
Erbium oxide (Er₂O₃) coating is one of the promising methods to restrict tritium permeation and the magneto hydrodynamic pressure drop for advanced breeding blanket systems. Er₂O₃ coating layer on large interior surface area of metal pipe is deposited by using metal organic chemical vapor deposition process. In this work, the influence of Cu²⁺ ion irradiation on microstructure of Er₂O₃ coating layer on stainless steel 316 (SUS 316) substrate by metal organic chemical vapor deposition methods was investigated using scanning electron microscopy, transmission electron microscopy observation and X-ray diffraction analysis. Microstructure observation of Er₂O₃ coating was carried out after 0.00-1.50 dpa Cu²⁺ ion irradiation at 298 K and 773 K. Scanning electron microscopy observation of the surface area on Er₂O₃ thin film revealed the crack generation on surface after Cu²⁺ ion irradiation. X-ray diffraction peaks were identified in Er₂O₃ after Cu²⁺ ion irradiation transmission electron microscopy observations, the formation of interlayer between Er₂O₃ coating and SUS substrate was confirmed. According to transmission electron microscopy-energy dispersive spectroscopy, the interlayer includes Fe and Cr.
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