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EN
Bilayer sandwich structures were fabricated by the sequential thermal evaporation of gold, copper phthalocyanine (CuPc), C_{60} and gold onto sap­phire substrates. When the current-voltage characteristics of a freshly made device are measured in an atmosphere of argon, fairly strong rectification is observed. When the bilayer device is exposed to ammonia vapor, the recti­fication slowly decreases and almost disappears. If the device is then placed under vacuum and the ammonia removed, the initial conditions slowly re­turn. We attribute the rectification to the formation of a p-n junction.
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