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EN
A series of iron oxide nanocatalysts were prepared using an ultrasonically assisted co-precipitation technique. Molybdenum promoted Fe3O4 and Fe2O3 were prepared from the original materials by wet impregnation using a solution of ammonium molybdate. The catalysts were tested in the liquid phase oxidation of benzene at atmospheric pressure and at 60°C using molecular oxygen. Phenol yields between 7% and 14.5% were obtained. The major products were pyrogallol and catechol.
EN
To study the influence of ozonation on the activated carbon adsorption, a model solution containing approximately 8 mg/dm3 of humic acid and approximately 1 mg/dm3 of phenol has been ozonated, and then adsorption kintetics and adsorption isotherm experiments have been performed. The applied ozone doses ranged from 1 to 3 mg O3/dm3, and a contact time was 1 min. In the adsorption experiments, the commercial activated carbon CWZ-30 (Gryfskand Sp. z o.o., Hajnówka, Poland) has been used. Phenol adsorption under equilibrium conditions was determined by the Freundlich isotherm equation, and the modified Freudlich isotherm equation has been employed for the determination of humic acid equilibrium adsorption. The applied oxidation conditions resulted in color, chemical oxygen demand (COD), total organic carbon (TOC) and UV254 absorbance removal, by 4 - 13%, 3 - 6%, 3 - 7%, respectively. After ozonation, phenol concentration decreased by 6 - 23%. These changes in the model solution did not affect the humic acid adsorption, however, they deteriorated phenol adsorption.
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EN
This paper deals with the problem of the photocatalytic reactor construction. The supported TiO2 on γ- Al2O3 modified with Mo or V addition was used as the photocatalyst, whereas phenol and formaldehyde were chosen as the model pollutants. The counter - current contact of reagents and catalysts is the main advantage of the construction and enables a significant COD reduction of the highly concentrated wastewaters.
EN
Biaryls are the potential source of synthetic drugs. The present study describes the synthesis of a series of functionalized biphenyl derivatives (3a-3g) using Pd-catalyzed Suzuki coupling reaction. The experimental results revealed the facile synthesis of biphenyl derivatives (3a-3g) with notably high yield (80-88 %). Density functional theory (DFT) studies were performed by Gaussian 09 software in order to rationalize the selectivity of coupling at C-Br bond instead of C-Cl bond. In addition of synthesis, the biological activities (biofilm inhibition, hemolytic and anti-thrombolytic) of these novel compounds were investigated. These results exhibited good biofilm inhibition (5.86-65.8 %), hemolytic (1.32-30.1 %) and anti-thrombolytic activities (9.64-42.5 %), indicating the potential use of these compounds for pharmaceutical applications.
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