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Excess thermodynamic quantities of D2O water calculated from its Raman O−D stretching spectra

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Georgiev M., Goutev N., Nickolov Z., Georgiev G.
Open Physics
|
2005
|
vol. 3
|
issue 1
104-114
EN
Excess thermodynamic functions of D2O water have been calculated from the vibrationally decoupled O−D stretching spectra of very dilute solutions of HOD in H2O. Comparison of the results with reference calorimetric data for water showed a good correspondence for excess heat capacity above the melting point of ice. The excess enthalpy at the melting point also coincides well with latent heat of melting.
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