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EN
The paper presents the results of an analysis of the changes of the mass and amounts of organic substances and combustible elements in a biodegradation process. The prepared sample of organic waste constituted the material used for the tests. The composting process was being carried out for 9 weeks in field conditions. The samples for analyses were collected every 7 days. The content of a biodegradable fraction was determined according to the procedure described in the standard of PN - EN 15169: 2007 "Characterization of waste-Determination of loss on ignition in waste, sludge and sediments". Reduction of the mass of the organic waste during the composting process amounted to 35%. A significant content of organic fraction (about 60-70% after 9 weeks) remains in the composted waste; and the content of combustible elements is reduced (by about 30%.)
EN
Heavy metals determination in manures provides beneficial information to predict the availability and the potential contamination of environment. Therefore, a study was carried out to investigate heavy metals changes in livestock manure during a co-composting process. The metals were stepwise fractionated into exchangeable, adsorbed, organically bound, carbonate precipitated and residual forms by extracting with 0.5M KNO3, de-ionized water, 0.5M NaOH, 0.05M Na2EDTA and 4M HNO3, respectively. During the extraction process, the amount of metals remained highly dependent on an extraction method and stage of manure composting. Extractions released heavy metals contents in the final composted manure as Zn > Cu > Pb > Cr > Ni > Cd. Irrespective of the days of composting, extracting agents differed in the order HNO3 > Na2EDTA > NaOH > KNO3 > H2O for all heavy metals. Higher concentrations of heavy metals were observed during the early stages of composting. Conversely, there was a progressive increase in the concentrations of K, Ca and Mg during composting of manure. Total C in the manure reduced with composting days.
EN
Biodegradation of plastics bags advertised as 100%-degradable or certified as compostable was tested in composting conditions. Samples were placed into frames and inserted into one clamp within the compost pile to investigate the biodegradation. The plastics bags were obtained from chain stores in the Czech Republic and Poland. The shopping bags were made of HDPE with the TDPA additive (sample 2), PP with an addition of pro-oxidants (d2w) (samples 1, 3) and materials certified as compostable (starch, polycaprolactone) (samples 4, 5, 6, 7). Control sample (cellulose filtering paper, sample 8) was to check the potential of biological decomposition in the tested environment. At the end of the 12-week experimental period it was found that the polyethylene samples with the additive (samples 1, 2, 3) had not been decomposed, their colour had not changed and that no degradation neither physical changes had occurred (did not biodegrade). Samples certified as compostable (samples 4, 5, 6, 7) were decomposed. The results at the municipal compost facility demonstrate that the compostable plastics biodegrade and polyethylene samples with the additive did not biodegrade in compost.
PL
Badano biodegradację plastikowych toreb reklamowych ulegających w 100% rozkładowi oraz certyfikowanych jako kompostowalne w warunkach kompostowania. W celu oceny biodegradacji próbki zostały umieszczone w ramach, a następnie w materiale przeznaczonym do kompostowania. Plastikowe torby są dostępne w sieci sklepów w Czechach, jak również w Polsce. Badaniu poddano osiem próbek. Jedną z nich była jednorazowa torba wykonana z folii HDPE z dodatkiem TDPA (próbka 2). Kolejne torby były wykonane z polietylenu z dodatkiem oxo-biodegradacji d2w (próbki 1, 3). Cztery próbki posiadały certyfikat kompostowalności (próbki 4, 5, 6, 7). Próbka ósma była próbką kontrolną (celulozowy papier filtracyjny, próbka 8), która miała na celu sprawdzenie potencjału biologicznego rozkładu badanego środowiska. Test został przeprowadzony w warunkach kompostowni przemysłowej. Pod koniec 13-tygodniowego okresu doświadczalnego stwierdzono, że próbki z polietylenu (próbki 1, 2, 3) nie uległy rozkładowi, ich barwa się nie zmieniła oraz że nie ma zmian fizycznych potwierdzających degradację. Próbki posiadające certyfikat kompostowalności (próbki 4, 5, 6, 7) uległy rozkładowi w różnym stopniu. Z przeprowadzonego doświadczenia wynika, że kompostowalne torby uległy rozkładowi, a torby wykonane z polietylenu z dodatkiem TDPA oraz d2w nie ulegają rozkładowi w kompoście.
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