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Physicochemical characteristics of 2-, 3- and 4-methylpyridinium tetrachloroferrates(III)

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Wyrzykowski D., Wera M., Sikorski A., Jacewicz D., Chmurzyński L.
Open Chemistry
|
2011
|
vol. 9
|
issue 6
1096-1101
EN
The crystal structure of 2-methylpyridinium tetrachloroferrate(III) was determined. The iron cation is tetracoordinated by chloride anions, and it adopts a slightly distorted tetrahedral coordination with three angles smaller, two almost equal and one larger than the tetrahedral. The compound is isostructural with its 3-, and 4-methylpyridinium analogues. The thermal properties of 2-, 3- and 4-methylpyridinium tetrachloroferrates(III) have been studied using TG and DSC techniques. The compounds exhibit a high stability in the melt. [...]
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