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  1. 1 Open Chemistry

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  1. 1 2011

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  1. 1 Isidorov V.

  2. 1 Kotowska U.

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Partition coefficients of ketones, phenols, aliphatic and aromatic acids, and esters in n-hexane/nitromethane

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Kotowska U., Isidorov V.
Open Chemistry
|
2011
|
vol. 9
|
issue 5
813-824
EN
Liquid-liquid partition is used in sample preparation and in countercurrent and liquid-liquid chromatographic separations. Partition coefficients are widely used in toxicology, environmental, and analytical chemistry. The K hn determination procedure for the n-hexane/nitromethane system was optimized and partition coefficients for 99 ketones, esters and trimethylsilyl derivatives of phenols, aliphatic and aromatic acids were determined. For 130 compounds, K hn values were predicted using mathematical relationships between K hn and other physicochemical and structural parameters. [...]
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