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The synthesis, structure and physical properties of lanthanide(III) complexes with nicotinic acid

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Hojnik N., Kristl M., Golobič A., Jagličić Z., Drofenik M.
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issue 2
220-226
EN
This article reports the synthesis of novel, rare-earth coordination complexes with nicotinic acid. Three compounds with the general formula Ln2[(C5H4NCOO)6(H2O)4] (Ln = Yb, 1; Ln = Gd, 2; Ln = Nd, 3) were prepared from relatively cheap and readily available reactants. Their compositions and structure were characterized by IR spectroscopy and single-crystal X-ray diffraction. The magnetic and thermogravimetric properties were also studied. The complexes consist of centrosymetric, dimeric molecules having all six nicotinato ligands coordinated with the central atom in the bidentate mode. The coordination environment of the Ln3+ for all three compounds is 8. Here we describe the crystal structure of Yb and Gd complexes with nicotinic acid.
2
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The structural, magnetic, hydrogenation and electrode properties of REMg2Cu9−xNix alloys (RE=La, Pr,Tb)

100%
Pavlyuk V., Rozycka-Sokolowska E., Marciniak B., Paul-Boncour V., Dorogova M.
Open Chemistry
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2011
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vol. 9
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issue 6
1133-1142
EN
The LaMg2Cu9, PrMg2Cu9, LaMg2Cu4Ni5, PrMg2Cu4Ni5 and TbMg2Cu6Ni3 alloys were prepared for the investigations of crystal structure, magnetic and hydrogen storage properties. The magnetic properties of several REMg2Cu9−xNix compounds have been studied up to 9 T and from 2 to 300 K. Tb compounds show a ferrimagnetic (with Ni) or antiferromagnetic (without Ni) behaviour, which can be attributed to the Tb magnetic structure. At high temperature a paramagnetic Curie Weiss behaviour is observed and the effective moment corresponds to that of Tb. A magnetic contribution of Pr moment is observed in both Pr compounds, with larger magnetization for PrMg2Cu4Ni5 and a transition at 3 K. The hydrogen absorption occurs at 95 bar for LaMg2Cu9 (3 H f.u.−1) and above 2 bars for LaMg2Cu4Ni5 (1.6 H f.u.−1). The effect of Cu-Ni substitution on the electrochemical properties of LaMg2M9 ternary alloys was investigated leading to maximum discharge capacity of 250–310 mAh g−1. [...]
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Optimization of synthesis conditions and the study of magnetic and dielectric properties for MgFe2O4 ferrite

100%
Druc A., Dumitrescu A., Borhan A., Nica V., Iordan A., Palamaru M.
Open Chemistry
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2013
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vol. 11
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issue 8
1330-1342
EN
Nano-sized magnesium ferrites were synthesized by the sol-gel auto-combustion method using a variety of chelating/combustion agents: tartaric acid, citric acid, cellulose, glycine, urea and hexamethylenetetramine. The original purpose of this work was the synthesis of nano-sized magnesium ferrite by using, for the first time, cellulose and hexamethylenetetramine as chelating/combustion agents. Synthesized samples were subjected to different heat treatments at 773 K, 973 K and, respectively 1173 K in air. The disappearance of the organic phase and nitrate phase with the spinel structure formation was monitored by infrared absorption spectroscopy. Spinel structure, crystallite size and cation distribution were evaluated by X-ray diffraction data. The morphology of as-prepared powders was studied using scanning electron microscopy. The magnetic and dielectric properties were studied for the obtained samples. [...]
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