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EN
The purpose of this study was to evaluate the effect of glycerol supplementation on aerobic and anaerobic exercise performance in sedentary subjects and athletes. The glycerol supplement treatments were as follows: 40 volunteers were selected and divided into two groups, sedentary and exercise groups. These two groups were further subdivided into two groups. The first group, the placebo (S), only consumed water; the second group (GS) consumed glycerol followed by water. Neither of these groups did any exercise for 20 days. The third and fourth groups consisted of the exercise group subjects; they were required to perform a 20-m shuttle run test every day for 20 days. The third group’s subjects, the placebo (E), only consumed water. The last group (GE) consumed glycerol followed by water. The Astrand Cycle Ergometer Test (ACET) was performed, and the Cosmed K4b2 portable gas analysis system was used to determine the aerobic capacity, while the Wingate Anaerobic Power Test (WAPT) was performed to determine the level of anaerobic power. The 20 Meter Shuttle Run Test (20MSRT) was performed after glycerol supplementation throughout the 20 days, and the exercise periods and distances were recorded. The glycerol supplement was found to have an increasing effect on aerobic and anaerobic performance in GS, E and GE. A similar effect was found for the covered distances and time in the same groups. However, an adverse effect was found on body weight.
EN
Nickel catalysts supported on Al2O3, CeO2 and ZrO2 were prepared by wet impregnation method and evaluated in steam reforming of glycerol. The catalysts were characterized by chemical composition, textural analysis, crystalline structure and reducibility. The structural characterization of the catalysts revealed a good dispersion of Ni particles using the Al2O3 support, needing higher reduction temperature. The reactions were performed at 500°C with 10 vol.% glycerol solution in a continuous flow reactor. All catalysts showed conversions close to 100%. The selectivity to gas products and formation of liquid by-products were found to be dependent on the type of support. The H2 selectivity showed the following trend: ZrO2 > Al2O3 ≈ CeO2. The catalyst supported on CeO2 showed low activity for water-gas shift reaction, with the highest CO selectivity. All catalysts presented a low formation of CH4. In the liquid phase some by-products were identified (hydroxyacetone, acetic acid, lactic acid, acetaldehyde, acrolein and ethanol) and secondary reaction routes were proposed. Coke formation was higher on Ni/Al2O3 catalyst, but no deactivation was observed during 8 h of reaction.
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