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Evaluation of Rheological Behaviour upon Recycling of an Ethylene Vinyl Acetate Copolymer by Means of Twin-Screw Extrusion Process

100%
Fatih Ergin M., Aydin I.
Acta Physica Polonica A
|
2017
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vol. 131
|
issue 3
542-544
EN
Recycling of many polymers has gained a spectacular importance mainly because of its environmental and economical benefits. Ethylene vinyl acetate is one of the thermoplastics used directly as a final product and indirectly as an additive within many other polymeric materials. There has been limited research work on recycling of polymers even though recycling in industry has shown a spectacular growth in the last decade. It is the aim of this study to investigate and to evaluate the rheological behaviour of an ethylene-vinyl acetate copolymer resin upon recycling. For this purpose, original ethylene vinyl acetate granules were processed five cycles by using a twin-screw extruder and their rheological analysis was performed by means of an AR-G2 rheometer (TA Instruments), with a parallel-plate geometry, under a steady state condition. It was found that the rheological measurements of copolymer ethylene vinyl acetate exhibited a shear thinning constitutive behavior, obeying Carreau-Yasuda rheological constitutive model. The changes in flow and oscillatory shear measurements under different processing conditions were also determined in detail and results are reported in the paper.
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Processing of Integral-Skin Cellular Polymeric Composites in Rapid Rotational Foam Molding

72%
Pop-Iliev R.
Acta Physica Polonica A
|
2011
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vol. 120
|
issue 2
292-297
EN
In order to survive the competition, the processing cycle time and the energy consumption of the rotational foam molding process must be reduced to a fraction of its current levels without compromising product quality. This paper introduces a novel extrusion-assisted rotational foam molding process for the manufacture of rotational moldings having adjacent, but clearly distinct, layers of an integrated solid (non-cellular) skin boundary layer encapsulating a cellular core structure, consisting of identical or compatible polyolefin grades, that achieves significant savings in processing cycle time duration and energy consumption. It introduces non-chilled extruded foam as a foamed core-forming material, in real time, directly into a uni-axially rotating hot mold through a dedicated mold "injection" port onto the already formed un-foamed soft skin layer.
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