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Salt effect on the enthalpy of mixing of 2-propanol + acetic acid at 303.15 K

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Tamilarasan R., Baffna S., Anand-Prabu A., Dharmendira-Kumar M.
Polish Journal of Chemical Technology
|
2009
|
vol. 11
|
issue 4
20-23
EN
This paper presents the effect of two dissolved inorganic salts (zinc chloride, ZnCl2 and ammonium chloride, NH4Cl) on the enthalpy of mixing (HE) of 2-propanol + acetic acid binary system measured at 303.15 K using an isothermal displacement calorimeter with vapour space. A decreasing trend in the excess enthalpy of mixing values in the presence of ZnCl2 and NH4Cl indicate the endothermic behavior of this system. The Redlich-Kister equation has been used to fit the experimental HE data. The deviations from the ideal value and binary parameters were calculated and reported.
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