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Magnetism of Higher Borides

100%
Acta Physica Polonica A
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2008
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vol. 113
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issue 1
231-234
EN
Magnetism of borides which contain the B_{12} icosahedra as a structural building block are attracting increasing interest since they exhibit unexpectedly strong magnetic interactions, despite being magnetically dilute f-electron insulators. The magnetic behavior among the different compounds has also been found to be diverse. The f-electron dependence of magnetic B_{12} icosahedra borides is compared, and found to be different from conventional mechanisms. The TbB_{25} system is also investigated further and the transition is assigned to a typical antiferromagnetic transition.
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issue 5
1042-1044
EN
Point-contact spectroscopy studies of the superconducting energy gap and the electron-phonon coupling mechanism are performed on the boron rich YB_6 and ZrB_{12} single crystals. The obtained values of the superconducting energy gaps suggest the strong coupling with 2 Δ/k_{B}T_{c}≈ 4.2 for YB_6 and 2 Δ/k_{B}T_{c}≈ 4.15 for ZrB_{12}. We have observed the dominant soft phonon modes mediating superconductivity in the both samples at energy ≈ 8 meV for YB_6 and ≈ 11 meV in ZrB_{12}, respectively.
3
51%
EN
Magnetic ordering in TbB_{66} and GdB_{66} was investigated at very low temperatures. Measurements of ac susceptibility have shown rather clear features of magnetic ordering below 1 K, at 0.34 K for TbB_{66} and at 0.20 K for GdB_{66}. However, no clear evidence of long range magnetic order was found by neutron scattering experiments. Reasons leading to these observations are discussed.
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Influence of Pressure on Superconductivity in YB_{6}

33%
EN
Magnetoresistivity measurements on a superconducting system of YB_{6} (T_c ≈7.5 K) down to 60 mK at hydrostatic pressures up to 47 kbar are presented. The superconducting transition temperature, as well as the third critical field H_{c3} reveal a linear decrease with increasing pressure with slopes of d ln H_{c3}/dp=-1.1 %/kbar, and d ln T_c/dp=-0.59 %/kbar. From the latter a critical pressure, p_c ≈ 170 kbar, at which T_c vanishes, is determined.
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