Spectral investigations of someμ-oxo-dimer complexes of trivalent metals (Mn, Fe) with two different ligands: tetraphenylporphyrin and tetranaphthylporphyrin (TNP), and fullerene (C_{60} and C_{70}) complexes withμ-oxobis[5,10,15,20-tetraarylporphyrinatometal (III)] (TXP-M)_2O dimer, where M = Fe, Mn and X = phenyl or naphthyl, are presented. Discussion of the main electronic and vibrational bands observed in the UV-Vis-IR and Raman spectra of both classes of fullerene-porphyrin systems is given. Experimental data are completed with the quantum chemical calculations of MnTNP^+ component.
We propose a new method of obtaining a photoluminescence spectrum of a single quantum dot in a self-assembled system of CdTe/ZnTe quantum dots. The method is based on the resonant excitation of a coupled dots pair. The comparison of the spectra in resonance and out of resonance enables the identification of a well-isolated lines related to the excitonic p-states. The application of the method allows the basic characterisation of a quantum dot, including the measurements of linear anisotropy, the excitation power dependence, and the analysis of the photoluminescence in the magnetic field.
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