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Magneto-Structural Correlations in Cu(en)_2SO_4 - a new Magnet with Two-Dimensional Triangular Arrangement of Cu(II) ions

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Kajňaková M., Orendáčová A., Orendáč M., Feher A., Mal'arová M., Trávníček Z.
Acta Physica Polonica A
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2008
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vol. 113
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issue 1
507-510
EN
Cu(en)_2SO_4 (en = 1, 2-diaminoethane) was synthesized and its crystal structure determined. From a crystallographic point of view, the compound might represent an example for the realization of a S =1/2 Heisenberg magnet on a two-dimensional spatially anisotropic triangular lattice. Magnetic susceptibility and magnetization studies were performed to analyze the magneto-structural correlations and to characterize the magnetic subsystem of the present compound. The results indicate the presence of antiferromagnetic interactions between magnetic ions with zJ/k_B≈-14.6 K and short-range order near 7 K.
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