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EN
A study of low energetic modes in the resonance Raman spectra of the organic superconductors α_{t}-(BEDT-TTF)_{2}I_{3} (T_{c} = 8 K) and β-(BEDT-TTF)_{2}IAuI (T_{c} = 4 K) in the temperature range of 1.5-100 K was per­formed. In both materials, a strong vanishing of low energetic phonon bands (at 30 cm^{-1} and 40 cm^{-1} for α_{t}-(BEDT-TTF)_{2}I_{3} and at 27 cm^{-1} and 33 cm^{-1} for β-(BEDT-TTF)_{2}IAuI) below 71 was observed. For the sym­metric stretching mode of the I¯_{3} and the IAuI¯ anion at 120 cm^{-1} no change below T, was found. In addition, wavelength dependent measure­ments on α-(BEDT-TTF)_{2}I_{3} were performed, indicating that the modes around 30 cm^{-1} are probably librational modes of the BEDT-TTF molecules.
EN
The Fermi surfaces and effective masses of (BEDO-TTF)_{2}ReO_{4}(H_{2}0) and κ-(BEDT-TTF)_{2}I_{3} were investigated by Shubnikov–de Haas (SdH) and de Haas–van Alphen (dHvA) measurements in magnetic fields up to 27 T in the temperature range from 0.5 K to 4.2 K. Two small closed pockets (0.7% and 1.5% of the first Brillouin zone) are observed in (BEDO-TTF)_{2}ReO_{4}(H_{2}0) corresponding very well with two cross-sectional areas of the Fermi surfaces obtained for a hole and an electron pocket from tight binding calculations. In contrast, in κ-(BEDT-TTF)_{2}I_{3} two rel­atively large closed sections (13% and 85% of the first Brillouin zone) of the Fermi surfaces are observed, again confirming the tight binding calcu­lations. For κ-(BEDT-TTF)_{2}I_{3} in magnetic fields above 12 T the effective mass for the larger orbit, as obtained from the temperature dependence of the SdH-oscillation amplitudes, is magnetic field dependent as long as the field is arranged perpendicular to the conducting planes (Θ = 0°). In con­trast, from dHvA measurements - which were performed by turning the magnetic field by 27° with respect to the SdH experiments - the observed effective mass is field independent. We suppose that the occurrence of anyons at temperatures below 1 K and in fields above 12 T might be the reason for the observed field dependence of the effective mass in the SdH investigations under the special angle 0°.
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