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EN
In this study, tungsten-vanadium carbide-graphite and tungsten-vanadium carbide-titanium carbide-graphite composites (W-VC-TiC-C) which can be used in high-tech equipment were investigated against different gamma radioisotopes. The composite materials were produced via mechanical alloying method in two groups; one of them includes 93% tungsten (W), 6% vanadium carbide (VC) and 1% graphite (C) which was synthesized during three different alloying times (6, 12, 24 hours). Other group of the samples were composited as 91% tungsten, 6% vanadium carbide (VC), 2% titanium carbide (TiC) and 1% graphite (C) which has also three different alloying times (6, 12, 24 hours). Gamma transmission technique was used in the experiments to investigate the gamma attenuation properties of the composite materials. Linear and mass attenuation coefficients of the samples were determined in the experiments and theoretical mass attenuation coefficients were calculated using widely acknowledged XCOM computer code. The experimental mass attenuation coefficients and calculated theoretical results were compared and evaluated with each other. Results showed that gamma attenuation coefficients of the composite materials dependent on alloying time. It can be concluded that increasing the tungsten ratio causes higher linear attenuation coefficient which decreases with increasing gamma energies.
EN
Boralyn (Al/B₄C) composite material is produced chiefly of boron carbide and aluminum. Boron Carbide is an important material for the nuclear industry due to high neutron absorption cross-section. This composite is used as shielding materials to absorb neutrons in the nuclear reactors and control road materials. In this study we investigated Al/B₄C composites against gamma radiation. For that purpose, 5 wt.%, 10 wt.%, 15 wt.% and 20 wt.% reinforcement content were investigated. Cs-137 gamma radioisotope source which has 662 keV gamma energy photons were used. For each material, linear and mass attenuation coefficients were calculated. Theoretical mass attenuation coefficients were calculated from XCOM computer code. The theoretical results were compared with experimental results. The results were showed that increasing the amount of Boron Carbide compound content of boralyn composite material decrease the linear and mass attenuation coefficient of materials
EN
This study was aimed to determine kinetic and thermodynamic behaviors of selenium on modified bentonite and activated carbon. Thermodynamic parameters such as enthalpy ΔH, free energy change ΔG and entropy change ΔS of selenium adsorption suggested that the adsorption of Se(IV) on activated carbon and organic-inorganic modified bentonite was exothermic and endothermic process, respectively. The experimental data fitted very well the pseudo-second-order kinetic model for both adsorbents.
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