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Amorphous Bi-Ge-S(Se) Systems Studied by X-Ray Ge K Emission and Absorption Bands

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Drahokoupil J., Drbohlav I., Polčik M., Tichý L.
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The X-ray Ge K absorption (emission) bands were measured in the stoichiometric glass system (GeS_{2})_{x}(Bi_{2}S_{3})_{1-x} (x = 0 ÷ 0.5) and in the Ge_{20}Bi_{y}Se_{80-y} system (y = 0, 7 and 13). The results do not confirm the existence of the Ge-Bi bond and they imply that the GeS_{2}-clusters are formed in both studied systems.
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