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An analytic equation of state based on analytic mean-field potential approach and application to three phases of metallic Zirconium

100%
Tian R., Sun J., Yang W., Xue X., Yu F.
Open Physics
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2008
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vol. 6
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issue 3
704-710
EN
The analytic mean-field approach (AMFP) was applied to study the thermodynamic properties of Zirconium (Zr). The analytic expressions for the Helmholtz free energy, internal energy and equation of state have been derived. The formalism for the case of the Morse potential is used in this work. The four potential parameters are determined by fitting the molar volume of the three phases of Zr. The calculated molar volume of α, β and ω Zr are in fairly good agreement with the available experimental data. The results presented in this paper verify that the AMFP is a useful approach to study the thermodynamic properties of Zr. Furthermore, we predict the variation of the relationship of free energy and internal energy versus the molar volume at various temperatures and the dependence of the bulk modulus, the thermal expansion coefficient and the heat capacity on temperature at zero pressure of α, β and ω Zr.
2
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The q-exponential family in statistical physics

84%
Naudts J.
Open Physics
|
2009
|
vol. 7
|
issue 3
405-413
EN
The notion of a generalized exponential family is considered in the restricted context of non-extensive statistical physics. Examples are given of models belonging to this family. In particular, the q-Gaussians are discussed and it is shown that the configurational probability distributions of the micro-canonical ensemble belong to the q-exponential family.
3
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Magnetic properties of the mixed spin-5/2 and spin-3/2 Blume-Capel Ising system on the two-fold Cayley tree

84%
Yessoufou R., Amoussa S., Hontinfinde F.
Open Physics
|
2009
|
vol. 7
|
issue 3
555-567
EN
We use exact recursion relations to study the magnetic properties of the half-integer mixed spin-5/2 and spin-3/2 Blume-Capel Ising ferromagnetic system on the two-fold Cayley tree that consists of two sublattices A and B. Two positive crystal-field interactions Δ1 and Δ2 are considered for the sublattice with spin-5/2 and spin-3/2 respectively. For different coordination numbers q of the Cayley tree sites, the phase diagrams of the model are presented with a special emphasis on the case q = 3, since other values of q reproduce similar results. First, the T = 0 phase diagram is illustrated in the (D A = Δ1/J,D B = Δ2/J) plane of reduced crystal-field interactions. This diagram shows triple points and coexistence lines between thermodynamically stable phases. Secondly, the thermal variation of the magnetization belonging to each sublattice for some coordination numbers q are investigated as well as the Helmoltz free energy of the system. First-order and second-order phase transitions are found. The second-order phase transitions become sharper and sharper when D A or D B increases. The first-order transitions only exist for some appropriate non-zero values of D A and/or D B. The corresponding transition lines never connect to the second-order transition lines. Thus, the non-existence of tricritical points remains one of the key features of the present model. The magnetic exponent β 0 of the model is estimated and found to be ¼ at small values of D A = D B = D and β 0 = ½ at large values of D. At intermediate values of D, there is a crossover region where the magnetic exponent displays interesting behaviours.
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