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Optical Transition, Excitation, and Emission Properties of Poly(N-Vinlycarbazole) Blended with Poly(Vinylidene Fluoride-co-Hexafluoropropene) and Polyvinylpyrrolidone

100%
Alias A., Zabidi Z., Harun M., Yahya M., Ali A.
Acta Physica Polonica A
|
2015
|
vol. 127
|
issue 4
1430-1433
EN
We present the results concerning the excitation and emissions spectra of Poly (N-carbazole) (PVK) blended with poly(vinylidene fluoride-co-hexafluoropropene), (PVDF-HfP) and polyvinylpyrrolidone (PVP). Thin films of PVK blended with PVDF-HfP (PVK:PVDF-HfP) and PVP (PVK:PVP) were prepared using doctor blade technique on spectrosil substrate. The influences of polymer blends on the excitation and emission spectra were observed under UV excitation source of a xenon lamp. The result shows a discrepancy in the maximum excitation and emission for each sample. The possible energy transfer and recombination mechanisms have been related with singlet-singlet semi-empirical INDO electronic calculation and FTIR measurements.
2
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Optical Transition, Excitation, and Emission Properties of Poly(N-Vinlycarbazole) Blended with Poly(Vinylidene Fluoride-co-Hexafluoropropene) and Polyvinylpyrrolidone

100%
Alias A., Zabidi Z., Harun M., Yahya M., Ali A.
Acta Physica Polonica A
|
2015
|
vol. 127
|
issue 4
1075-1078
EN
We present the results concerning the excitation and emissions spectra of poly(N-carbazole) (PVK) blended with poly(vinylidene fluoride-co-hexafluoropropene), (PVDF-HfP) and polyvinylpyrrolidone (PVP). Thin films of PVK blended with PVDF-HfP (PVK:PVDF-HfP) and PVP (PVK:PVP) were prepared using doctor blade technique on spectrosil substrate. The influences of polymer blends to the excitation and emission spectra were observed under UV excitation source of a xenon lamp. The result shows a discrepancy in the maximum excitation and emission for each samples. The possible energy transfer and recombination mechanisms have been related with singlet-singlet semi-empirical INDO electronic calculation and FTIR measurements.
3
Content available remote

First Principles Calculation of ε-Phase of Solid Oxygen

86%
Kamaruddin K., Abedin A., Zabidi N., Yahya M., Taib M., Rosli A.
Acta Physica Polonica A
|
2016
|
vol. 129
|
issue 4
468-471
EN
The electronic structures of ε-phase of solid oxygen (O₂)₄ are studied within the framework of density-functional theory. The intriguing molecule has been known to have magnetic properties at room temperature by applying pressure. Nevertheless, until now there was no evidence of band structure studied in the antiferromagnetic behaviour of (O₂)₄. We report a comparison study for spin and non-spin polarization orbital which suggests that this ferromagnetic configuration of (O₂)₄ could not be seen experimentally, and antiferromagnetic configuration of (O₂)₄ was seen at higher pressure of about 10 GPa. The antiferromagnetic state transforms into the superconducting state as the sample temperature decreases. The results can serve as a useful approximation in studying general features of the electronic structure. The (O₂)₄ clusters are reported in the Raman study, having significant absorption at 1516 cm¯¹ below infrared region.
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