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EN
The vibrational dynamics of water around glycine was investigated by using Raman spectroscopy and inelastic neutron scattering. Experiments of deuterated glycine versus deuterium were performed as comparison. The study shows that for glycine, the exchange of proton-deuteron on the active NH_3^+ side was easy, whereas there was hardly exchange on the CH_2 side. Comparing different proportion of glycine vs. water molecules we obtained that the presence of water hardly changes the main features of glycine illustrating its hydrophobic character. The intralayer hydrogen bonds of glycine crystal are difficult to be replaced due to its stronger bond than water.
EN
Self-assembled face-centered cubic FePt nanoparticles were embedded into the oxide capping layer using the atomic layer deposition technology. The effect of the oxide-matrix layer on the structure, mono-dispersibility, and magnetic properties of the FePt/oxide composite thin films was investigated. Experimental results suggest that the protection of the oxide-matrix capping layer can effectively inhibit the grain growth and particle aggregation, and preserve the ordered domains of the FePt nanoparticles during the L 1_0 ordering transition through annealing. The combination of the atomic layer deposition capping layer and self-assembled FePt nanoparticles provides a new potential approach to fabricate the ultrahigh-density magnetic recording media.
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