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The potassium holmium double tungstate was prepared by using top seeded solution growth technique. Structural investigations have been performed at room temperature. The KHo(WO_4)_2 single crystal belongs to the monoclinic space group C2/c with the unit-cell parameters: a = 10.624(2) Å, b = 10.352(2) Å, c = 7.5434(15) Å, β = 130.78(3)^{o}, and Z = 4. The atomic coordinates, isotropic and anisotropic displacement parameters and interionic distances for the studied structure were determined.
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