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  1. 1 Open Chemistry

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  1. 1 2003

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  1. 1 Ksenofontov V.

  2. 1 Kustov L.

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Transformations of xylenes in trimethylammonium hydrochloride-Aluminum chloride ionic liquid

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Ksenofontov V., Kustov L.
Open Chemistry
|
2003
|
vol. 1
|
issue 3
305-313
EN
Isomerization of m-, o-and p-xylenes in the presence of trimethylammonium hydrochloride-AlCl3 ionic liquid with different composition was studied. Ionic liquids with the following ammonium salt: AlCl3 molar ratios were used: 1∶2, 1∶1.5 and 1∶1.25. It was shown that isomerization of xylenes proceeds under mild conditions at temperatures from 60°C to 110°C. It was found that the activity and selectivity of the ionic liquids depends on their composition. The most effective catalyst was the ionic liquid with the ammonium salt: AlCl3 molar ratio equal to 1∶2.
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