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Structure and permanent electric dipole of para-fluoroaniline in gaseous phase

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Rahim M., Ghannam L., Antoine R., Dugourd P., Rayane D., Broyer M., Karamé I.
Open Chemistry
|
2013
|
vol. 11
|
issue 3
325-329
EN
Abstract By coupling a matrix assisted laser desorption source to an electric beam deflection setup, we have measured the permanent electric dipole moment of the isolated para-fluroaniline PFAN (FC6H4NH2) molecule in the ground state. This measurement of the electric dipole of an isolated push-pull molecule is unique. The experimental value is compared to two different calculations and the structure of the system is discussed. Graphical abstract [...]
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