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EN
In this paper the results of the investigation of magnesium removal, from zinc concentrate derived from zinc-lead ore enrichment plant, have been presented. The characteristics of the initial concentrate and the occurrence forms of dolomite in this material are estimated. It was found that magnesium is collected in the finest fraction of the initial material. The influence of chemical treatment and flotation on the quality improvement of zinc concentrate is determined. This method permits to obtain zinc concentrate containing below 0,3% Mg and about 0,7% Ca.
EN
Zinc oxide derived from processing of the slime obtained in an industrial process of electrolytic zinc obtaining was leached with the aqueous sulfuric acid solution. The effect of temperature and time on the extent of leaching was determined. The conditions lead to zinc recovery of about 90%. It was found that the extent of arsenic leaching did not depend upon the time and temperature of leaching. Next the conditions of the solution purification procedure were determined. It was found that jarosite formation as well as the degree of arsenic removal is connected with trivalent iron concentration in the solution.
EN
In this paper the results of investigation of magnesium removal from raw zinc concentrate have been presented. The raw materials derive from ZG Trzebionka and ZGH Bolesław. The differences in zinc and magnesium contents are characteristic of these materials. The experiments were carried out in the periodical reactor at 25°C using the H2SO4 solution of 20, 50, and 70%(v/v) concentration. The weight ratio of the solid phase to the liquid phase was 1:10 and 1:2. On the basis of the experimental results it can be stated that the application of sulphuric(VI) acid leaching permits to increase the zinc yield in Zn-Pb ore processing. This method permits to obtain zinc concentrate containing more than 60% Zn and MgO below 0.3% and CaO about 1.4%.
EN
In this paper the result of the study on chemical leaching of zinc concentrate with H2SO4 solution was presented. The object of this work was to assess the effect of some parameters such as acid concentration, the leaching agent amount /stoichiometry amount or excess of acid were applied/, reaction time and temperature on the process. The investigation was performed as a active experiment according to Hartley's plan. The process optimisation procedure was based on the fuzzy logic system. Mainly, the parameters such as magnesium leaching efficiency and zinc losses were taken into account. It was stated that the highest magnesium leaching efficiency of 77.8% with low Zn-losses was reached when H2SO4 solution concentration was 2.5% for 20%-excess of acid, at temperature 25°C and process time of 1 hour.
EN
The paper deals with the verification of the floatability of pyrolytic oils, which were obtained through the pyrolysis of waste, namely mixed plastics, tyres and waste rubber in combination with black coal from Lazy Mine, and classical collector Montanol 551 in black coal flotation. Black coal from ČSA OKD, a.s. coal preparation plant was used for flotation tests. The results imply that it is possible to produce collectors from waste materials which may be applied in the flotation of black coal. Next, the paper focused on the identification of a suitable combination of pyrolytic oils and Montanol 551 in order to reach ash content in the concentrate below 10%.
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