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Core Polarization Effects in the Relativistic Quantum-Defect-Orbital Theory

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Bielińska-Wąż D., Martin I., Karwowski J.
Acta Physica Polonica A
|
1994
|
vol. 85
|
issue 5
805-812
EN
The quantum-defect-orbital method has been reformulated in order to include both relativistic effects and the electron correlation described by a core polarization potential. All quantities appearing in this formulation may be evaluated analytically. A comparison with experimental results demonstrates, on one hand, significance of the relativity-correlation corrections and, on the other, inadequacy of the relativistic quantum-defect-orbital approach when indirect relativistic effects are important, i.e. when atoms contain closed shells of d electrons.
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