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EN
Using the general-purpose relativistic atomic structure package based on the fully relativistic multiconfiguration Dirac-Fock method, we have reported the electric dipole transition (E1) parameters such as wavelengths, weighted oscillator strengths, transition rates (or probabilities) and line strengths for 5s-5p and 5p-5d transitions in Xe²⁺. In calculations, the Breit interaction and quantum electrodynamic effects have been included as perturbations. The calculated values for energy levels including valence and core-valence correlation have been compared with other available experimental and theoretical values in literature. Our transition results can provide useful data for, in particular, experimental works in future.
2
81%
Open Physics
|
2008
|
vol. 6
|
issue 4
771-774
EN
Excited electronic states of the Au3 cluster are studied within the shape-consistent small-core relativistic pseudopotential model using many-body multipartitioning perturbation theory. Vertical transition energies and dipole moments are evaluated. For highly symmetric isomer, these theoretical results are in reasonable agreement with spectroscopic data from experiments.
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