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Studies of Phase Diagram and Glass Transitions of a Liquid Crystal with Ferro- and Antiferroelectric Phases

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Kolek Ł., Massalska-Arodź M., Majda D., Suchodolska B., Zalewski S.
Acta Physica Polonica A
|
2013
|
vol. 124
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issue 6
909-912
EN
Based on the results of the differential scanning calorimetry, of transmitted light intensity measurements and of texture observations the phase diagram of 4-(6-heptafluorobutanoiloxyhexyloxy)biphenyl-4'-carboxylate(S)-4-(methyloheptyloxy-1-carbonyl)-phenyl (4H6) was obtained. The following phases were identified on cooling: isotropic, smectic A, smectic C*, smectic C*_{A} phases and a highly ordered phase called SmX and its glass. During heating transformation from glass of SmX to SmX phase and then transition to a metastable Cr2 phase, evolving to the more stable Cr1 phase, were observed. On further heating SmC*_{A}, SmC* and Sm phases were identified. When Cr2 was cooled, a glass transition was also observed.
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