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  1. 1 Acta Physica Polonica A

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  1. 1 1996

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  1. 1 Bukietyńska K.

  2. 1 Mondry A.

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Spectroscopy Studies of Erbium and Dysprosium Acetate Single Crystals

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Mondry A., Bukietyńska K.
Acta Physica Polonica A
|
1996
|
vol. 90
|
issue 1
233-238
EN
Electronic absorption spectra of erbium and dysprosium acetate single crystals were measured. The intensities of 4f-4f transitions were calculated and the Judd-Ofelt Ω_{λ} parameters evaluated. Heavy lanthanide acetates differ from other lanthanide carboxylate compounds by relatively high "hypersensitive" transition intensities and the Ω_{2} parameters. These results are discussed in terms of a stronger polarization effect which can be explained by the distinctly shorter Ln-OH_{2} bond in comparison with the Ln-OOC bond in the investigated system.
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