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Crystal Structure and Magnetic Properties of Pyrrhotite-Type Compounds Fe_{7-y}V_{y}S₈

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Selezneva N., Ibrahim P., Toporova N., Sherokalova E., Baranov N.
Acta Physica Polonica A
|
2018
|
vol. 133
|
issue 3
450-452
EN
The pyrrhotite-type compounds Fe_{7-y}V_{y}S₈ have been synthesized and studied by means of the X-ray diffraction and magnetization measurements in order to reveal how the substitution of V for Fe affects the crystal structure, phase transition and magnetic properties. The growth of the V content in Fe_{7-y}V_{y}S₈ results in changes of the crystal structure and leads to a sharp decrease in the resultant magnetization, non-monotonous change of the coercive field and reduction of the magnetic ordering temperature. Unlike ferrimagnetic ordering in pyrrhotite Fe₇S₈ the compound V₇S₈ is observed to exhibit a Pauli-paramagnetic behaviour.
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