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Kinetics of the formation and structure of oligoperoxide nanolayers and grafted polymer brushes on glass plate surface

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Kostruba A., Zaichenko A., Mitina N., Rayevska K., Hertsyk K.
Open Physics
|
2008
|
vol. 6
|
issue 3
454-461
EN
Functional oligoperoxide surfactants and coordinating oligoperoxide metal complexes were studied as modifiers of glass flat plates to provide the localization of radical forming sites and other functional fragments in adsorbed polymeric layers of a nanoscale thickness. Both the kinetics of the coating formation and properties of the nanolayers witness the dependence of the packing density of oligoperoxide molecules in the coatings on the oligoperoxide natures, concentrations and conditions of the sorption modification. The availability of definite amount of peroxide groups in formed nanolayer provides the possibility of controlled radical graft polymerization initiated from modified surface leading to reliable surface protection, functionality and targeted surface hydrophilic-hydrophobic properties.
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