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Raman studies of Pd-C nanocomposites

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The results of studying palladium-carbon (Pd-C) nanocomposites using Raman spectroscopy are presented. This method has been used for studying samples having various palladium content, prepared by a one-step Physical Vapour Deposition (PVD) process and a Chemical Vapour Deposition (two-step PVD/CVD) process using different process parameters. For samples obtained by PVD, the vibration bands characteristic of C60 fullerene molecules were observed in the spectra, whereas for layers obtained by PVD/CVD, the Raman spectra displayed mainly D and G bands characteristic solely of the prescence of graphite-like layers’ vibrations. The analysis of the obtained Raman spectra reveals that its shape is affected by many parameters including type of substrate, temperature, and the percentage content of Pd in the studied layer. The quantitative analysis of spectra for layers obtained using the PVD/CVD process shows a difference in the relative intensity of bands D and G, reflecting the different degrees of amorphisation in the investigated nanocomposites.
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Topography and nanomechanical properties of Pd-C films

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Atomic force microscopy (AFM) topographical studies and results of nanoindentation experiment for several palladium-carbon films (Pd-C film) deposited on various substrates and with varying palladium content are presented. Pd-C films were prepared by a physical vapor decomposition (PVD) process and next were modified by a chemical vapor decomposition (CVD) method to obtain carbonaceous porous structure with dispersed palladium nanograins and a variation in roughness. The dependence of film topography on the kind of substrate such as Al2O3, Mo polycrystalline foil and fused silica was studied by AFM. Nanomechanical properties such as hardness and the reduced indentation modulus were determined by nanoindentation. A comparison of these values for films with different Pd content deposited on various substrates is presented.
EN
In this work, the differences in nanomechanical properties, topography and morphology of carbonpalladium (C-Pd) films were studied. These films were prepared with a Physical Vapour Deposition method on various substrates with different technological parameters. We show that duration of the PVD process is a crucial factor affecting the palladium content in these films. The differences in thickness of films depend on the distance between source boats and substrates. The nanomechanical properties of C-Pd films were studied with nanoindentation. Their topography and morphology was ascertained with Atomic Force Microscopy and Scanning Electron Microscopy. It was found that the mechanical properties of C-Pd films depend on the content of palladium and on the morphology and topography of these films. The various types of carbon-palladium films containing palladium nanograins incorporated in a carbon matrix that were, investigated in this paper, seem to be promising materials for numerous applications.
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