Vacancy transfer probabilities from K to L shell were measured using I_{Kβ}/I_{Kα} intensity ratios for six elements in the atomic region 16 ≤ Z ≤ 22. The K X-rays from the targets excited by 5.96 keV (1.85 GBq ^{55}Fe filtered annular source) incident photon were obtained using a high resolution PGT model Si(Li) detector. Theoretical values were calculated using radiative and radiationless transition rates of these elements. The measured values of η_{KL} were compared with the theoretical ones. Reasonable agreement was typically obtained between present and theoretical values.
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