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  1. 1 2014

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  1. 1 Latika A.

  2. 1 Šebesta R.

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Enantioselective Michael additions of aldehydes to nitroalkenes catalyzed with ionically tagged organocatalyst

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Šebesta R., Latika A.
Open Chemistry
|
2014
|
vol. 12
|
issue 3
416-425
EN
Enantioselective organocatalytic Michael additions affords useful building blocks for many biologically and medicinally relevant compounds. Ionically-tagged diphenylprolinol silyl ether efficiently catalyzes several Michael additions of aldehydes to nitroalkenes in ionic liquids. The Michael additions work well in ionic liquids; yields up to 95% and enantioselectivities up to 95% ee were achieved. Furthermore, in some cases, the catalytic system was reusable.
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